Four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site

Buss, Joshua A.; Agapie, Theodor

doi:10.1038/nature16154

Cited by 102 publications

(101 citation statements)

References 36 publications

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“…In contrast, the signal observed at δ C 254 ppm was indeed comparable to the NMR shifts observed in Scandium carbide Sc 2 C 2 (δ C 253 ppm) and Yttrium carbide Y 2 C 2 (δ C 257 ppm) reported by Yamazaki et al [41] and Zhang et al [42]. An exceedingly rare 13 C-NMR resonance published by Buss et al [43] observed a carbon resonance exhibited at δ C 546 ppm from a novel molybdenum carbide complex, thus the unusually sharp signal observed at δ C 307 ppm could also be interpreted as a metal carbide resonance.…”

Section: Chemical Characteristicssupporting

confidence: 83%

Characterisation of the Chemical Composition and Structural Features of Novel Antimicrobial Nanoparticles

et al. 2017

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Three antimicrobial nanoparticle types (AMNP0, AMNP1, and AMNP2) produced using the TesimaTM thermal plasma technology were investigated and their compositions were determined using a combination of analytical methods. Scanning electron micrographs provided the morphology of these particles with observed sizes ranging from 10 to 50 nm, whilst FTIR spectra confirmed the absence of polar bonds and organic impurities, and strong Raman active vibrational bands at ca. 1604 and 1311 cm−1 ascribed to C–C vibrational motions were observed. Carbon signals that resonated at δC 126 ppm in the solid state NMR spectra confirmed that sp2 hybridised carbons were present in high concentration in two of the nanoparticle types (AMNP1 and AMNP2). X-ray powder diffraction suggested that AMNP0 contains single phase Tungsten carbide (WC) in a high state of purity and multiple phases of WC/WC1-x were identified in both AMNP1 and AMNP2. Finally, X-ray photoelectron spectral (XPS) analyses revealed and quantified the elemental ratios in these composite formulations.

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Section: Chemical Characteristicssupporting

confidence: 83%

Characterisation of the Chemical Composition and Structural Features of Novel Antimicrobial Nanoparticles

et al. 2017

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“…The terphenyldiphosphine ligands introduced by Agapie combine this property with strongly σ‐donating phosphines. Notable examples include mono‐, di‐, and trinuclear complexes of Ni, dinuclear d 9 ‐Pd, M 2 ‐carbonyl cores of Fe, Co, and Ni, and complexes of Mo in which the ligand also functions as a two‐electron reservoir …”

Section: Introductionmentioning

confidence: 99%

Redox and Acid–Base Properties of Binuclear 4‐Terphenyldithiophenolate Complexes of Nickel

Koch

Berkefeld

Schubert

et al. 2016

Chemistry A European J

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This work reports on the redox and acid–base properties of binuclear complexes of nickel from 1,4‐terphenyldithiophenol ligands. The results provide insight into the cooperative electronic interaction between a dinickel core and its ligand. Donor/acceptor contributions flexibly adjust to stabilize different redox states at the metals, which is relevant for redox reactions like proton reduction. Proton transfer to the [S2Ni2] core and Ni−H bond formation are kinetically favored over the thermodynamically favored yet unproductive proton transfer to ligand.

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“…33,34 This unusual phenomenon allowed unprecedented reactivity including the change of up to five oxidation states of a dinitrogen complex and four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site. 35 Our group has taken a different approach in order to achieve the goal of coordination flexibility and redox activity (Chart 1g, h). [27][28][29] Instead of using a purely organic ligand, we reasoned that an organometallic ligand should serve as an excellent candidate.…”

Section: Introductionmentioning

confidence: 99%

Reactivity and Properties of Metal Complexes Enabled by Flexible and Redox-Active Ligands with a Ferrocene Backbone

Huang

Diaconescu

2016

Inorg. Chem.

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Our group has focused on the organometallic chemistry of rare-earth metals and actinides for a decade. By installing ferrocene diamide ligands at electropositive metal centers, we have been able to disclose unprecedented reactivity toward aromatic N-heterocycles, arenes, and other small molecules such as P 4 . Systematic studies employing X-ray crystallography, spectroscopy, cyclic voltammetry, and DFT calculations revealed that the ferrocene backbone could stabilize the electron-deficient metal through a donor-acceptor type interaction. Most noteworthy is that this interaction can be readily turned on or off by the addition or removal of a Lewis base. In addition to its flexible coordination, the redox active nature of the ferrocene backbone enabled us to explore redox-switchable transformations. The introduction of ferrocene-based ligands into organolanthanide chemistry not only helped to study intriguing fundamental problems but also led to fruitful chemistry including small molecule activation and controlled co-polymerization reactions.3

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Four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site

Cited by 102 publications

References 36 publications

Characterisation of the Chemical Composition and Structural Features of Novel Antimicrobial Nanoparticles

Characterisation of the Chemical Composition and Structural Features of Novel Antimicrobial Nanoparticles

Redox and Acid–Base Properties of Binuclear 4‐Terphenyldithiophenolate Complexes of Nickel

Reactivity and Properties of Metal Complexes Enabled by Flexible and Redox-Active Ligands with a Ferrocene Backbone

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