Four metal–organic architectures from a triphenyl-tricarboxylic acid: synthesis, crystal structures, and catalytic features

Chen, Jinwei; Li, Xiong; Ai, Feng; Zou, Xun-Zhong; Liu, Yu; Gu, Jin‐Zhong

doi:10.1007/s11243-022-00513-8

Transit Met Chem

2022

DOI: 10.1007/s11243-022-00513-8

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Four metal–organic architectures from a triphenyl-tricarboxylic acid: synthesis, crystal structures, and catalytic features

Jinwei Chen¹,

Xiong Li²,

Feng Ai³

et al.

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2024

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Cited by 2 publications

References 40 publications

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Synthesis and catalytic performance of One-Dimensional coordination polymers for Knoevenagel condensation under green conditions

Brite Vieira,

Gonçalves de Souza,

Braga Ferreira

et al. 2024

Inorganica Chimica Acta

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Synthesis and catalytic performance of One-Dimensional coordination polymers for Knoevenagel condensation under green conditions

Brite Vieira,

Gonçalves de Souza,

Braga Ferreira

et al. 2024

Inorganica Chimica Acta

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Terphenyl-Tricarboxylate Coordination Polymers: From Hydrothermal Assembly to Structural Diversity and Catalytic Application

Zhang,

Gu,

Kirillova

et al. 2024

Crystal Growth & Design

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An aromatic tricarboxylic acid building block, [1,1′:3′,1″-terphenyl]-4,4″,5′tricarboxylic acid (H 3 tptca), was used as a versatile linker for assembling, under hydrothermal conditions, a series of 12 new coordination polymers (CPs) in the presence of supporting Ndonor ligands acting as mediators of crystallization. The obtained products were formulated as [Mn(μ-Htptca)(phen 11), and [Co 2 (μ 4 -tptca)(μ-bpb)(μ-OH)] n (12), wherein phen, 2,2′-bipy, 4,4′-bipy, bpe, H 2 biim, bpa, and bpb are 1,10-phenanthroline, 2,2′-and 4,4′bipyridine, 1,2-di(4-pyridyl)ethane, 2,2′-biimidazole, bis(4-pyridyl)amine, and 1,4-bis(pyrid-4yl)benzene, respectively. Crystal structures of CPs 1−12 reveal a broad diversity metal− organic networks that range from 1D chains (1, 2, 5, 6, and 8) to 2D layers (3, 4, 7, 9, and 11) and 3D nets (10 and 12), including the examples of interpenetrated, polycatenated, and topologically unique architectures. Structural features and catalytic properties of the obtained CPs were studied and discussed. In particular, a Zn(II) CP 8 acts as an efficient and recyclable heterogeneous catalyst for the mild cyanosilylation of benzaldehydes, leading to the formation of the corresponding cyanohydrin products in up to 99% yields. The obtained compounds widen a growing family of functional CPs driven by terphenyl-tricarboxylate linkers.

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Four metal–organic architectures from a triphenyl-tricarboxylic acid: synthesis, crystal structures, and catalytic features

Cited by 2 publications

References 40 publications

Synthesis and catalytic performance of One-Dimensional coordination polymers for Knoevenagel condensation under green conditions

Synthesis and catalytic performance of One-Dimensional coordination polymers for Knoevenagel condensation under green conditions

Terphenyl-Tricarboxylate Coordination Polymers: From Hydrothermal Assembly to Structural Diversity and Catalytic Application

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