2004
DOI: 10.1103/physrevlett.93.157008
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Four-Unit-Cell Superstructure in the Optimally DopedYBa2Cu3O6.92Superconductor

Abstract: Diffuse x-ray scattering measurements reveal that the optimally doped YBa2Cu3O6.92 superconductor is intrinsically modulated due to the formation of a kinetically limited 4-unit-cell superlattice, q(0)=(1/4, 0, 0), along the shorter Cu-Cu bonds. The superlattice consists of large anisotropic displacements of Cu, Ba, and O atoms, respectively, which are correlated over approximately 3-6 unit cells in the ab plane, and appears to be consistent with the presence of an O-ordered "ortho-IV" phase. Long-range strain… Show more

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Cited by 38 publications
(31 citation statements)
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“…The different periodicity seems to depend on the oxygen doping, as predicted theoretically 24 and supported experimentally by the fact that the undoped compound YBa 2 Cu 4 O 8 does not exhibit diffuse features. 25 However, the picture seems to be more complex and for optimally doped samples ͑O stoichiometry 6.92͒ a four unit cell superstructure, expected near 6.75 stoichiometry, has been observed, 30 and attributed either to phase separation or non-negligible Coulomb interactions. Furthermore, in underdoped compounds the observed diffuse scattering has been interpreted as the presence of charged stripes whose periodicity uses that of the underlying oxygen ordering in the Cu-O chains due to an anomaly in the evolution of the intensity at the pseudogap opening.…”
Section: Introductionmentioning
confidence: 99%
“…The different periodicity seems to depend on the oxygen doping, as predicted theoretically 24 and supported experimentally by the fact that the undoped compound YBa 2 Cu 4 O 8 does not exhibit diffuse features. 25 However, the picture seems to be more complex and for optimally doped samples ͑O stoichiometry 6.92͒ a four unit cell superstructure, expected near 6.75 stoichiometry, has been observed, 30 and attributed either to phase separation or non-negligible Coulomb interactions. Furthermore, in underdoped compounds the observed diffuse scattering has been interpreted as the presence of charged stripes whose periodicity uses that of the underlying oxygen ordering in the Cu-O chains due to an anomaly in the evolution of the intensity at the pseudogap opening.…”
Section: Introductionmentioning
confidence: 99%
“…While such period-4 (aka ortho-IV) oxygen order has, to our knowledge, not been reported in YBCO thin films, it has been observed in bulk YBCO at and above the optimal doping level2425. Like other oxygen orderings, the ortho-IV order persists well above room temperature (up to 500 K) and has a weak temperature dependence, with no anomaly observed at T c .…”
Section: Resultsmentioning
confidence: 58%
“…11 Figure 2 shows the typical butterfly pattern of this elastic distortion that has been observed in neutron scattering measurements of a polaron in the manganite LaMNO 3 and optimally doped YBa 2 Cu 3 O 6 superconductor. 13,14 Such interactions influence the collective behavior or selforganization of a system of polarons or charge distortions in a medium 15 and can affect the behavior of magnetoresistance or superconductivity. 16 The presence of π/4 orientations, where the compressional shear energy or U is zero, leads to twin domain walls oriented at π/4 angles and reflects in 2D the square symmetry of the parent phase in our example.…”
Section: Elastic Compatibility and Domain Structuresmentioning
confidence: 99%