Fourier-transform microwave and submillimeter-wave spectroscopy of chloroiodomethane, CH2ICl

Bailleux, S.; Ozeki, Hiroyuki; Sakai, S.; Ohteki, Toshiaki; Kania, P.; Duflot, Denis

doi:10.1016/j.jms.2011.09.002

Cited by 3 publications

(1 citation statement)

References 25 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Puzzarini et al and Bailleux et al have recently published the analysis of the rotational spectrum of fluoro- and chloro-iodomethane, respectively, while Kisiel et al reported that of CH 2 I 2 more than a decade ago . In order to complete the study of the rotational spectra of the CH 2 I X dihalospecies, where X = {F, Cl, Br, I}, we have investigated those of CH 2 79 BrI and CH 2 81 BrI in the microwave and millimeter-wave regions.…”

Section: Introductionmentioning

confidence: 99%

Fourier Transform Microwave and Millimeter-Wave Spectroscopy of Bromoiodomethane, CH₂BrI

et al. 2014

Self Cite

View full text Add to dashboard Cite

Bromoiodomethane, CH2BrI, is a molecule of natural origin emitted in significant amount into the marine boundary layer. It can easily be decomposed by solar radiation, releasing Br and I atoms in the troposphere, which in turn impacts the atmospheric chemistry. Spectroscopy is an invaluable tool to monitor species present in the atmosphere. Since no high-resolution spectroscopic studies are available for this dihalomethane, we have investigated the rotational spectra of the two bromine isotopologues of CH2BrI in its vibrational ground state in the microwave and millimeter-wave regions. Transitions of b-type have been recorded by Fourier transform microwave spectroscopy below 25 GHz while both a- and b-type spectral lines have been measured below 230 GHz. Observed transitions correspond to energy levels with J ≤ 132 and Ka ≤ 14. Molecular constants including those describing the nuclear quadrupole coupling tensors for (79)Br, (81)Br, and (127)I were accurately determined from the least-squares analysis of a total of 1873 distinct transition frequencies (of which 943 belong to the CH2(79)BrI isotopologue). An experimental (r0) structure of the title species has been derived from the two sets of rotational constants.

show abstract

Section: Introductionmentioning

confidence: 99%

Fourier Transform Microwave and Millimeter-Wave Spectroscopy of Bromoiodomethane, CH₂BrI

et al. 2014

Self Cite

View full text Add to dashboard Cite

show abstract

Molecules Containing One Carbon Atom

Vogt

2019

Structure Data of Free Polyatomic Molecules

View full text Add to dashboard Cite

Nuclear quadrupole coupling in SiH2I2 due to the presence of two iodine nuclei

Arsenault

Obenchain

Orellana

et al. 2017

Journal of Molecular Spectroscopy

View full text Add to dashboard Cite

Fourier-transform microwave and submillimeter-wave spectroscopy of chloroiodomethane, CH2ICl

Cited by 3 publications

References 25 publications

Fourier Transform Microwave and Millimeter-Wave Spectroscopy of Bromoiodomethane, CH₂BrI

Fourier Transform Microwave and Millimeter-Wave Spectroscopy of Bromoiodomethane, CH₂BrI

Molecules Containing One Carbon Atom

Nuclear quadrupole coupling in SiH2I2 due to the presence of two iodine nuclei

Contact Info

Product

Resources

About

Fourier-transform microwave and submillimeter-wave spectroscopy of chloroiodomethane, CH2ICl

Cited by 3 publications

References 25 publications

Fourier Transform Microwave and Millimeter-Wave Spectroscopy of Bromoiodomethane, CH2BrI

Fourier Transform Microwave and Millimeter-Wave Spectroscopy of Bromoiodomethane, CH2BrI

Molecules Containing One Carbon Atom

Nuclear quadrupole coupling in SiH2I2 due to the presence of two iodine nuclei

Contact Info

Product

Resources

About

Fourier Transform Microwave and Millimeter-Wave Spectroscopy of Bromoiodomethane, CH₂BrI

Fourier Transform Microwave and Millimeter-Wave Spectroscopy of Bromoiodomethane, CH₂BrI