FOURIER TRANSFORM MICROWAVE SPECTROSCOPY OF LiNH2 and NaNH2 (~X1A1): COMPARING QUADRUPOLE HYPERFINE INTERACTIONS

Abstract

Rotational spectra of LiNH 2 and NaNH 2 in their X1 A 1 ground electronic states have been recorded using pulsed-beam Fourier transform spectroscopy in the frequency range 22-58 GHz. These species were synthesized in a DC discharge by the reaction of ammonia and the respective laser-ablated alkali metal, in argon carrier gas. Observed transitions were analyzed with previously-measured millimeter-wave frequencies, improving previous rotational constants and determining the metal electric quadrupole hyperfine parameter, χ aa , for both species. We find that χ aa (Li) = 0.494 and χ aa (Na) = -7.688. We also compare our results to DFT calculations. A Townes-Dailey analysis of the quadrupole constants suggest that the bonding of the -NH 2 ligand to lithium and sodium is comparable.