Fractal microgeometry of original and hydgrogen-charged graphene multilayer films surface: research by the low-temperature sorption of nitrogen method

Abstract

Abstract. Changes in the surface microgeometry of multilayer graphene films, as a result of hydrogen adsorption (1% mass.), have been examined by the method of low-temperature fractal sorption of nitrogen. It is established that hydrogen atmosphere treatment leads to the significant development of graphene surface and lowers the first layer heat adsorption from 289 down to 260J/kg. There have been found out as well the overall mesopores concentration growth and pore size distribution function broadening. At that, the surface fractal dimension value has grown from 2,52 up to 2,67, which is to give us an evidence of the surface chaotization as a result of hydrogen withdrawal into the atmosphere and the graphene surface erosion.