“…As its value depends only on the type of bond that is being broken, the calculated values for glassy and crystalline silica should be similar. The surface energy of silica glass under N 2 atmosphere and at 300 K is reported (Wiederhorn, 1969) to be approximately 4.4 J m −2 ; while MD simulations ( Leed and Pantano, 2003) yield an area density of Si-O-Si bonds of 7.2 bonds nm −2 , resulting on an activation energy of 360 kJ mol −1 . This is remarkably consistent with monocrystalline α-quartz, with values of 310 and 340 kJ mol −1 [for cracks propagating on the a < 1120 > plane, on directions normal to the planes z < 0111 > and r < 1011 >, respectively] calculated using fracture (Atkinson, 1979;Timms et al, 2010) and bond density data (Bloss and Gibbs, 1963) under inert atmosphere.…”