“…A vast accumulation of literature in the fields of soil science, geosciences, and petroleum engineering has provided overwhelming evidence that solute transport in undisturbed subsurface media is often influenced by preferential flow coupled with matrix diffusion [Shuford et al, 1977;Shaffer et al, 1979;Frohne and Mercer, 1984;Abelin et al, 1987Abelin et al, , 1991Seyfried and Rao, 1987;Jardine et al, 1988Jardine et al, , 1990Jardine et al, , 1993a with grossly different sizes. At the field scale, techniques 4 and 5 are most practical for quantifying advective preferential flow and time-dependent diffusion into the soil and bedrock matrix [Abelin et al, 1987;Harvey et al, 1989Harvey et al, , 1993Harvey et al, , 1995Raven et al, 1988;Zuber, 1990, 1993;McKay et al, 1993aMcKay et al, , b, 1995Sanford and Solomon, 1998;Jaynes and Horton, 1998].…”