Herein, a study of phosphate synthesis reactions with triethyl phosphate, phosphorous pentoxide and mixed alcohols is described. The synthesized phosphates are used as gelling agents in LPG fracturing fluids. By this study, a phosphate product with good performance has been obtain by screening different combination of alcohols and various reaction conditions including the ratios of reactants, reaction temperatures and reaction times. The LPG fracturing fluid prepared with the phosphate product we optimized maintains a viscosity of 200 mPa s for 1.5 h at 90 °C and 170 s −1 shear rate.