Recently it was discovered that null hypersurfaces can develop caustics outside the event horizon of super-entropic Kerr-AdS black holes, in contrast to the usual Kerr-AdS case. In this work we explore a few more examples of black hole spacetimes in which such exterior caustics can develop. If a closed null curve is present, e.g., in the case of Taub-NUT and the "transunital" Kerr-AdS spacetimes, then it coincides with a null hypersurface caustic (NHC) of a minimal separation parameter. Thus a spacetime on the verge of forming closed timelike curves could develop a caustic. Known examples of super-entropic black holes also have exterior NHC, although such spacetimes are free of closed null/timelike curves. Nevertheless the relationship between closed causal curves, NHC, and superentropy is not straightforward. This is best illustrated with the BTZ black string, which for some choices of the warp factor in the extra dimension and the value of the charge, can be super-entropic. However, even those that are not super-entropic can admit NHC outside the horizon.