Fragmentation Reactions of Bridged Heterocyclic Phosphorus Compounds as a Source of Low-Coordination Species

Quin, Louis D.; Szewczyk, Jerzy; Marsi, B. G.; Wu, Xiaoping; Kisalus, John C.; Pete, Béla

doi:10.1080/03086648708080569

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2015

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“…The mechanism of the Baeyer–Villiger oxidation was studied by quantum chemical calculations . It was found that the oxaphosphabicyclo[2.2.2]octene derivatives 6A and 6B underwent fragmentation to provide metaphosphonate 7 (Y = Ph, Me) on heating or UV irradiation, which phosphonylated the alcohol added to the mixture prior to the fragmentation (Scheme ) . The products were phosphonic acid‐esters ( 8 ).…”

Section: Introductionmentioning

confidence: 99%

Fragmentation-Related Phosphonylation of Nucleophiles Utilizing P-Alkyl 2,3-oxaphosphabicyclo[2.2.2]octene 3-oxide Precursors

2015

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Section: Introductionmentioning

confidence: 99%

Fragmentation-Related Phosphonylation of Nucleophiles Utilizing P-Alkyl 2,3-oxaphosphabicyclo[2.2.2]octene 3-oxide Precursors

2015

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ChemInform Abstract: Fragmentation Reactions of Bridged Heterocyclic Phosphorus Compounds as a Source of Low‐Coordination Species.

et al. 1987

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Convenient synthesis of 1‐alkoxy‐1,2‐dihydrophosphinine 1‐oxides by ring enlargement

Keglevich

Brlik

Janke

et al. 1990

Heteroatom Chemistry

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The addition of dichlorocarbene to the double bond of I -alkoxy-dihydrophosphole oxides and subsequent thermolysis of the adduct so obtained affords mixtures of the two double bond isomers of alkoxy-dihydrophosphinine oxides, i f the latter step is carried out in the presence of triethylamine. Experimental data support the involvement of a cationic intermediate during the opening of the cyclopropane ring. A simplified procedure for the preparation of the starting dihydrophospholes is also presented.

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Fragmentation Reactions of Bridged Heterocyclic Phosphorus Compounds as a Source of Low-Coordination Species

Cited by 4 publications

References 4 publications

Fragmentation-Related Phosphonylation of Nucleophiles Utilizing P-Alkyl 2,3-oxaphosphabicyclo[2.2.2]octene 3-oxide Precursors

Fragmentation-Related Phosphonylation of Nucleophiles Utilizing P-Alkyl 2,3-oxaphosphabicyclo[2.2.2]octene 3-oxide Precursors

ChemInform Abstract: Fragmentation Reactions of Bridged Heterocyclic Phosphorus Compounds as a Source of Low‐Coordination Species.

Convenient synthesis of 1‐alkoxy‐1,2‐dihydrophosphinine 1‐oxides by ring enlargement

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