Vibro-acoustic systems in aviation engineering could operate in a thermal environment and suffer from high-frequency dynamic excitations. The high-frequency vibro-acoustic problems are commonly solved by the Statistical Energy Analysis method, in which the Coupling Loss Factor is the key parameter for modeling vibro-acoustic systems. This work investigates the CLFs of vibro-acoustic systems under thermal environment. First, based on the modal data considering different thermal effects, the modal CLFs between structural modes and acoustic modes are predicted by the Statistical modal Energy distribution Analysis. Then, the CLFs between the structural subsystem and the acoustic subsystem are calculated. The simulation models employed in this research include the coupled plate-cavity system and the cylindrical shell-cavity system. The influence of thermal effects on the CLFs is discussed. For the investigated cases, in which the boundaries of structural susbsystem are set to simply supported, the results demonstrate that the CLFs decrease with increasing temperature when only the temperature-dependent material properties are considered. However, when only the additional stress stiffness is considered, the CLFs experience a more dramatic decrease compared to when only the temperature-dependent material properties are taken into account. Moreover, when both effects are considered, the influence of the additional stress stiffness has a leading effect on the CLFs. The proposed method can be conveniently applied to various vibro-acoustic systems operating in the thermal environment.