Characteristics of rotational earthquake ground motions and their effects on structural response are not yet well-defined. Recording rotational ground motions directly in free field is in its infancy, and simultaneous sixcomponent earthquake measurements are being accumulated slowly. A six-degree-of-freedom (6DOF) ground motion observation system was installed in the Garner Valley Downhole Array (GVDA), a very well-characterized and wellinstrumented geotechnical array in Southern California. Since 2008, six-component free-field earthquake ground motions have been recorded from hundreds of earthquakes with a relatively wide range of hypocentral distances and magnitudes. In this paper, analysis was conducted to develop the characteristics of these measured rotational ground motions. Linear relationships between peak rotation velocity and peak ground acceleration were found, similar to previous 6DOF measurements in Taiwan and Japan. Ratios of rotation to translation as a function of hypocentral distance show larger ground rotations at closer distance, and that rotational ground motions tend to attenuate more rapidly than corresponding translational ground motions. Measured rotational motions show differences from estimations using elastic plane wave theory when using simple local apparent wave velocities. Finally, preliminary empirical relationships for rotational response spectra are estimated for earthquake engineering applications.