In this paper we study some analytic properties of bi-free additive convolution, both scalar-and operator-valued. We show that using properties of Voiculescu's subordination functions associated to free additive convolution of operator-valued distributions, simpler formulas for bi-free convolutions can be derived. We use these formulas in order to prove several results about atoms of bi-free additive convolutions. Theor. Probab. 30 (2017) no. 1, 222-240.