A new generation of oxide crystals is emerging for electro-optic Q -switching or control of highpower pulsed lasers. Unlike the acousto-optic Q -switches in which the total turn-off time is limited by the duration of sound wave propagation (110-220 ns/mm) across the beam diameter, the electro-optic devices provide a short (<10 ns) response needed for minimum losses. Extinction ratios of better than 100 : 1 for electro-optic crystals ensure their reliable hold-off. By contrast, acousto-optic devices are characterized by single-pass dynamic losses of approximately 40%, which hinders their use in high-gain lasers. The basic principles of electro-optic Pockels cells are discussed. The performance characteristics of Q -switching for traditional electrooptic materials [deuterated potassium dihydrogen phosphate (DKDP), lithium niobate (LNB)] and other new electro-optic crystals, such as barium metaborate (BBO) and crystals belonging to the langasite (LGS) and potassium titanyl phosphate (KTP) families, are reviewed comparatively. Particular emphasis is placed on KTPtype electro-optic crystals, primarily on rubidium titanyl phosphate RbTiOPO 4 (RTP), which stand out in their ability to provide Q -switching at extremely high frequencies or repetition rates up to 200 kHz. The use of both X -and Y -oriented double crystals as Q -switches in order to combine large electro-optic coefficients and low quarter-wave hold-off voltages with excellent thermal stability of the device is considered.