“…The excessive use of fossil fuels in various sectors, such as the automobile, space industry, and agriculture, has created enormous concerns about their depletion, which forced researchers to think of alternative clean energy sources to reduce the dependency on fossil fuels and create the way toward futuristic sustainable, eco-friendly, and emission-free energy sources . Hydrogen (H 2 ) energy is considered an immensely auspicious and sustainable energy source because of its emission-free nature, abundant raw source, and high energy density of ∼287 kJ mol –1 . , H 2 energy is extensively used for industrial purposes such as petroleum refining and synthesis of ammonia and methanol as well as exploring its vast market and competition in the futuristic fuel cell-based vehicles for transportation. , Among numerous approaches, electrocatalytic water splitting is the utmost exciting, facile, and practical pathway compared with other methods due to its low cost and high-purity generation of clean and green hydrogen energy and oxygen during hydrogen and oxygen evolution reactions. , However, it offers a large overpotential in alkaline medium, which limits the development of scalable hydrogen energy production, making it expensive due to the intake of high electric energy. , On the other hand, the energy-saving electrocatalyst can stimulate proton reduction reaction at low overpotentials and Tafel slopes with improved reaction kinetics. , Basically, the catalysts’ electrocatalytic performance exclusively depends on available active centers, the inherent properties of active centers, and mass transport properties . Therefore, it is extremely desirable to cultivate high-standard electrocatalysts that are bifunctional for hydrogen and oxygen generation with exclusive merits such as excellent electronic transport properties, exceptional intrinsic activities, inexpensive, highly available active centers, and high stability in an alkaline medium.…”