In the past years, the most promising technology of producing ceramic coatings is a method of microarc oxidation. This method is characterized by universal properties of surface layer, which combines high-wear resistance, corrosion resistance, heat, and erosion resistance. The aim of the present work is to improve the tribological properties of microarc oxidation coatings using additional filling layer of coating as a thin film of polymer material. Ultra-high-molecular weight polyethylene was chosen as a polymer material. This composition material was tested under different friction conditions and showed significant decrease in friction coefficient for many friction pairs in different lubricant environment. The proposed technology of antifriction characteristics improvement of microarc oxidation coatings will significantly expand their application.