reduction and oxidation reactions occur at the corresponding electrode/electrolyte interface. As a result, the electrons flow orderly to do work with very high energy conversion efficiency. In the last two decades, a drastic change occurring in the world should be the rapid growth of information technology. The ever growing market of portable electrical apparatus raises the demand of portable and customized batteries as power sources. [1] Although the development of modern batteries like fuel cell and lithium ion (Li-ion) battery is also very fast, [2] monitoring, replacing and recycling trillions of batteries are especially arduous because of the vast distribution and short cycle lifetime. Besides, there are growing challenges from the dependence on limited fossil fuel, the demand of growing population and the concern about environmental degradation etc. So it is especially necessary to develop renewable power sources which are high-efficient, clean and sustainable.Triboelectrification (also named as contact electrification) is a wide effect around us, which usually needs to be prevented as the negative effect in many systems. In 2012, triboelectric nanogenerator (TENG) was invented to use triboelectricity for converting mechanical energy into electricity by Wang research group, which is a revolutionary breakthrough in the technology of energy conversion and utilization. [3] Traditional triboelectric generator can only accumulate static charges generated by triboelectrification, but there is no current unless there is a discharging. [4] However, the novel TENG can drive electrons to produce electricity via coalescing electrostatic induction with contact electrification. In the early period, TENG is mainly developed as micro-scale power source, which is used to supply for small portable electric apparatus. With the fast development of TENG, lots of work has been done to explore new approaches to effectively harvesting different forms of water power, namely macro-scale blue energy. [5] As for the development of nanotechnology, there are generally five steps in research: the fabrication of nanomaterials, the property of nanomaterials, the single nanodevice, an array of nanodevices, and the integration of system. With the new emergence of TENG, research in self-powered systems is fast expanding into many fields. [4,6] The rapid advancement of TENG gradually shifts its focus from the discrete devices to more complex integrated systems, which can perform multiple functions. Such integrated systems are expected to work sustainably Ever since the discovery of triboelectric nanogenerator (TENG) by Wang's group in January 2012, various breakthroughs have been achieved in the fundamental mechanisms of TENG as well as the demonstrated self-powered systems. TENG has shown many advantages in micro-scale energy harvesting for applications in sensors and portable devices. As a self-sufficient power source, TENG can be used in conjunction with electrochemical processes as self-powered electrochemistry without the use of exter...