Hydration lubrication plays a significant role in reducing
sliding
friction in various moving systems, from geological faults to molecular
materials systems, but the mechanism of lubrication on microscopic
friction remains poorly understood. In this study, through molecular
dynamics simulation, the dependence of the shear stress on normal
stress was investigated across varying water contents to illuminate
the influence of hydration lubrication on microscopic friction. Our
findings reveal that the adhesive force between mineral layers is
jointly governed by hydration film transition and H-bond characteristics,
subsequently governing the friction at the microscale. The variation
of the microscopic friction coefficient with water content shows two
distinct stages, with a critical transition from a 2-layer to 3-layer
water structure altering their correlation from positive to negative.
These insights provide a substantial contribution to understanding
the fundamental mechanism of hydration lubrication, opening new avenues
for exploration in the domain of microscopic friction.