2023
DOI: 10.1016/j.cej.2022.139172
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From biomass to humic acid: Is there an accelerated way to go?

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Cited by 37 publications
(13 citation statements)
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“…A significant signal located at 54 ppm can be assigned to the methoxy group, and the two peaks within the aromatic carbon region at 130 ppm and 144 ppm are attributed to the aromatic and unsaturated carbon, phenols and heterocyclic aromatic hydrocarbons, respectively. 21 These results revealed that lignin is the dominant aromatic structure in the A-HA spectrum, consistent with the results from the FT ICR-MS analysis. With the increase in the hydrothermal treatment time, the peak at 54 ppm gradually weakened, while the peak at 144 ppm gradually increased, suggesting that lignin was continuously involved in the polymerization reaction to form A-HA with a higher aromaticity.…”
Section: Resultssupporting
confidence: 88%
“…A significant signal located at 54 ppm can be assigned to the methoxy group, and the two peaks within the aromatic carbon region at 130 ppm and 144 ppm are attributed to the aromatic and unsaturated carbon, phenols and heterocyclic aromatic hydrocarbons, respectively. 21 These results revealed that lignin is the dominant aromatic structure in the A-HA spectrum, consistent with the results from the FT ICR-MS analysis. With the increase in the hydrothermal treatment time, the peak at 54 ppm gradually weakened, while the peak at 144 ppm gradually increased, suggesting that lignin was continuously involved in the polymerization reaction to form A-HA with a higher aromaticity.…”
Section: Resultssupporting
confidence: 88%
“…In addition, after being treated by KOH alone (Fig. 1c), the fluorescence intensities in regions II and IV decreased along with the appearance of slight fluorescence in region V, probably due to base-catalyzed hydrolysis and humification 29 . Notably, the fluorescence further moved towards region III (FLA) and V (HLA) after the simultaneous addition of PS and KOH (Fig.…”
Section: Resultsmentioning
confidence: 95%
“…The high pressure and temperature conditions promote the hydrolysis and decomposition of complex organic molecules, leading to the formation of simpler compounds. These compounds, such as sugars, amino acids, and fatty acids, undergo further reactions, including condensation and polymerization, ultimately resulting in the formation of HS . The hydrothermal reaction process can be optimized by controlling parameters such as temperature, pressure, reaction time, and solid-liquid ratio.…”
Section: Transformation Of Organic Waste Into Hsmentioning
confidence: 99%
“…This process facilitates the decomposition and conversion of organic compounds, resulting in the formation of polymeric HS. 102 During hydrothermal treatment, organic solid waste is immersed in a pressurized reactor and heated above the boiling point of water. The high pressure and temperature conditions promote the hydrolysis and decomposition of complex organic molecules, leading to the formation of simpler compounds.…”
Section: Conversion Processes and Technologiesmentioning
confidence: 99%