From manganese complexes to nano-sized manganese oxides as water-oxidizing catalysts for artificial photosynthetic systems: Insights from the Zanjan team

Najafpour, Mohammad Mahdi

doi:10.1016/j.crci.2015.12.009

Cited by 10 publications

References 133 publications

(142 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

Heterogeneous Sodium‐Manganese Oxide Catalyzed Aerobic Oxidative Cleavage of 1,2‐Diols

et al. 2017

View full text Add to dashboard Cite

The aerobic oxidative cleavage of 1,2-diols using aheterogeneous catalyst only based on earth-abundant metals manganese and sodium is reported for the first time.T his reusable catalyst cleaves av ariety of substrates into aldehydes or ketones with high selectivity.T he reaction requires small catalytic loadings and is performed under mild conditions using ambient pressure O 2 or air as the oxidant while producing water as the only by-product. Mechanistic investigations reveal am onodentate,t wo-electron oxidative fragmentation process involving aM n IV species.T he eco-friendly, innocuous catalyst is compatible with aw ide range of functional groups and conditions,making it highly competitive with classical reagents,such as periodic acid or lead tetraacetate,as apreferred method for activated 1,2-diols.

show abstract

Heterogeneous Sodium‐Manganese Oxide Catalyzed Aerobic Oxidative Cleavage of 1,2‐Diols

et al. 2017

View full text Add to dashboard Cite

show abstract

Heterogeneous Sodium‐Manganese Oxide Catalyzed Aerobic Oxidative Cleavage of 1,2‐Diols

et al. 2017

View full text Add to dashboard Cite

The aerobic oxidative cleavage of 1,2-diols using a heterogeneous catalyst only based on earth-abundant metals manganese and sodium is reported for the first time. This reusable catalyst cleaves a variety of substrates into aldehydes or ketones with high selectivity. The reaction requires small catalytic loadings and is performed under mild conditions using ambient pressure O or air as the oxidant while producing water as the only by-product. Mechanistic investigations reveal a monodentate, two-electron oxidative fragmentation process involving a Mn species. The eco-friendly, innocuous catalyst is compatible with a wide range of functional groups and conditions, making it highly competitive with classical reagents, such as periodic acid or lead tetraacetate, as a preferred method for activated 1,2-diols.

show abstract

Water oxidation by manganese oxides

Tavakolian

Salimi

Zand

et al. 2019

Water Oxidation Catalysts

View full text Add to dashboard Cite

From manganese complexes to nano-sized manganese oxides as water-oxidizing catalysts for artificial photosynthetic systems: Insights from the Zanjan team

Cited by 10 publications

References 133 publications

Heterogeneous Sodium‐Manganese Oxide Catalyzed Aerobic Oxidative Cleavage of 1,2‐Diols

Heterogeneous Sodium‐Manganese Oxide Catalyzed Aerobic Oxidative Cleavage of 1,2‐Diols

Heterogeneous Sodium‐Manganese Oxide Catalyzed Aerobic Oxidative Cleavage of 1,2‐Diols

Water oxidation by manganese oxides

Contact Info

Product

Resources

About