From Organotin Hydrides

Mathiasch, B.

doi:10.1002/9780470145234.ch48

Inorganic Reactions and Methods

1991

DOI: 10.1002/9780470145234.ch48

|View full text |Cite

From Organotin Hydrides

B. Mathiasch¹

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2009

Publication Types

Select...

Article2

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

References 28 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Knüpfung von Thiostannat‐Sn‐Sn‐Bindungen in Lösung: In‐situ‐Bildung des gemischtvalenten funktionalisierten Komplexes [{(RSn^IV)₂(μ‐S)₂}₃Sn^III₂S₆]

et al. 2009

View full text Add to dashboard Cite

Im Tageslicht kondensiert das Doppeldecker‐artige Thiostannat [(RSnIV)4S6] (1, R=CMe2CH2COMe) zum gemischtvalenten Komplex [{(RSnIV)2(μ‐S)2}3SnIII2S6] (2, siehe Bild), der (formal) SnIII‐ neben SnIV‐Zentren enthält, wie durch Mößbauer‐Spektroskopie und DFT‐Rechnungen bestätigt wurde. 2 weist sechs funktionelle CO‐Gruppen für weitere Reaktionen an der Ligandenhülle auf, und die Bildung scheint über einen komplizierten konzertierten Mechanismus zu verlaufen.

show abstract

Knüpfung von Thiostannat‐Sn‐Sn‐Bindungen in Lösung: In‐situ‐Bildung des gemischtvalenten funktionalisierten Komplexes [{(RSn^IV)₂(μ‐S)₂}₃Sn^III₂S₆]

et al. 2009

View full text Add to dashboard Cite

show abstract

Thiostannate Tin–Tin Bond Formation in Solution: In Situ Generation of the Mixed‐Valent, Functionalized Complex [{(RSn^IV)₂(μ‐S)₂}₃Sn^III₂S₆]

et al. 2009

View full text Add to dashboard Cite

In broad daylight: The double-decker thiostannate [(RSn(IV))(4)S(6)] (1, R = CMe(2)CH(2)COMe) condenses to form [{(RSn(IV))(2)(mu-S)(2)}(3)Sn(III)(2)S(6)] (2; see picture). This mixed-valent complex, which formally contains both Sn(III) and Sn(IV) atoms as confirmed by Mössbauer spectroscopy and DFT calculations, forms by a complicated, concerted mechanism. Additionally, 2 provides six carbonyl groups for further derivatization.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

From Organotin Hydrides

Cited by 2 publications

References 28 publications

Knüpfung von Thiostannat‐Sn‐Sn‐Bindungen in Lösung: In‐situ‐Bildung des gemischtvalenten funktionalisierten Komplexes [{(RSn^IV)₂(μ‐S)₂}₃Sn^III₂S₆]

Knüpfung von Thiostannat‐Sn‐Sn‐Bindungen in Lösung: In‐situ‐Bildung des gemischtvalenten funktionalisierten Komplexes [{(RSn^IV)₂(μ‐S)₂}₃Sn^III₂S₆]

Thiostannate Tin–Tin Bond Formation in Solution: In Situ Generation of the Mixed‐Valent, Functionalized Complex [{(RSn^IV)₂(μ‐S)₂}₃Sn^III₂S₆]

Contact Info

Product

Resources

About

From Organotin Hydrides

Cited by 2 publications

References 28 publications

Knüpfung von Thiostannat‐Sn‐Sn‐Bindungen in Lösung: In‐situ‐Bildung des gemischtvalenten funktionalisierten Komplexes [{(RSnIV)2(μ‐S)2}3SnIII2S6]

Knüpfung von Thiostannat‐Sn‐Sn‐Bindungen in Lösung: In‐situ‐Bildung des gemischtvalenten funktionalisierten Komplexes [{(RSnIV)2(μ‐S)2}3SnIII2S6]

Thiostannate Tin–Tin Bond Formation in Solution: In Situ Generation of the Mixed‐Valent, Functionalized Complex [{(RSnIV)2(μ‐S)2}3SnIII2S6]

Contact Info

Product

Resources

About

Knüpfung von Thiostannat‐Sn‐Sn‐Bindungen in Lösung: In‐situ‐Bildung des gemischtvalenten funktionalisierten Komplexes [{(RSn^IV)₂(μ‐S)₂}₃Sn^III₂S₆]

Knüpfung von Thiostannat‐Sn‐Sn‐Bindungen in Lösung: In‐situ‐Bildung des gemischtvalenten funktionalisierten Komplexes [{(RSn^IV)₂(μ‐S)₂}₃Sn^III₂S₆]

Thiostannate Tin–Tin Bond Formation in Solution: In Situ Generation of the Mixed‐Valent, Functionalized Complex [{(RSn^IV)₂(μ‐S)₂}₃Sn^III₂S₆]