2010
DOI: 10.1063/1.3524513
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Frost formation and ice adhesion on superhydrophobic surfaces

Abstract: We study frost formation and its impact on icephobic properties of superhydrophobic surfaces. Using an environmental scanning electron microscope, we show that frost nucleation occurs indiscriminately on superhydrophobic textures without any particular spatial preference. Ice adhesion measurements on superhydrophobic surfaces susceptible to frost formation show increased adhesion over smooth surfaces with a strong linear trend with the total surface area. These studies indicate that frost formation significant… Show more

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Cited by 677 publications
(535 citation statements)
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“…31 The image reproduced in Figure 3b illustrates that frost will form indiscriminately on superhydrophobic surfaces that are characterized by spatially uniform intrinsic interfacial energies, compromising their liquid repellency. 31 Ice on frosted superhydrophobic surfaces can adhere more strongly than it does on chemically equivalent smooth surfaces 31 because this "Wenzel ice" has a larger interfacial area of interaction with the substrate. One possible strategy for combating this frost-driven transition to the Wenzel state is to control the condensate nucleation spatially.…”
Section: The Research Reported By Mishchenko Et Al In This Issue Furmentioning
confidence: 99%
See 1 more Smart Citation
“…31 The image reproduced in Figure 3b illustrates that frost will form indiscriminately on superhydrophobic surfaces that are characterized by spatially uniform intrinsic interfacial energies, compromising their liquid repellency. 31 Ice on frosted superhydrophobic surfaces can adhere more strongly than it does on chemically equivalent smooth surfaces 31 because this "Wenzel ice" has a larger interfacial area of interaction with the substrate. One possible strategy for combating this frost-driven transition to the Wenzel state is to control the condensate nucleation spatially.…”
Section: The Research Reported By Mishchenko Et Al In This Issue Furmentioning
confidence: 99%
“…One possible strategy for combating this frost-driven transition to the Wenzel state is to control the condensate nucleation spatially. 27 If the nucleation is constrained to the top portions of the surface texture, it might be possible to facilitate the formation of weakly adhered composite 31 or "Cassie ice" and prevent the formation of the strongly adhered Wenzel ice. A final challenge that must be overcome before textured superhydrophobic surfaces gain widespread use in anti-icing applications is the development of commercially viable fabrication processes.…”
Section: The Research Reported By Mishchenko Et Al In This Issue Furmentioning
confidence: 99%
“…the works by Antonini et al [ Wang et al [76] studied the effects of a nano-fluorocarbon coating on icing, which is depicted in fig.23. Sequential high-speed video images of droplet impact on dry and frosted superhydrophobic surfaces are shown in fig.24 (Varanasi et al [74]), demonstrating that frost alters the wetting properties of the surface. Anti-icing coating design cases with various roughness scales are illustrated in fig.25 (Xiao and Chaudhuri [78]).…”
Section: Investigating Icephobicitymentioning
confidence: 99%
“…For example 12 , it was established recently that hydrophilic surfaces with nanometer (nm)-scale roughness (smaller than the size of the first stable ice nuclei) and higher wettability display, up to an order of magnitude, longer freezing delays compared with typical superhydrophobic surfaces with larger hierarchical roughness and very low wettability. In practice, the efficacy of anti-icing materials can also be limited by the presence of frost on the surface 13,14 .…”
mentioning
confidence: 99%