Fiber-reinforced polymers (FRPs) are widely used within civil structural applications either for structural retrofitting or new constructions. This is due to their appreciable mechanical properties such as high stiffness and strength, resistance to environmental effects, as well low density. Through the years, such peculiarities have encouraged researchers to apply FRP cables within the design of prestressing systems, where steel cables are systematically adopted. However, the brittleness intrinsic to FRP materials necessitates additional efforts to design the anchorage devices. In fact, tendons are here subjected to stress peaks, which need to be controlled in order to prevent the premature failure of the cable. Following this goal, authors recently studied an optimized split-wedge anchorage, for 12 mm-diameter pultruded-carbon-fiber-reinforced polymer (PCFRP) tendons, adopting double-angle (DA) wedges, and compared its performance with a single-angle (SA) wedge configuration. Tensile tests were performed on 3 SA and 2 DA prototypes, respectively, through a universal testing machine: the DA configuration exploited the average cable capacity (257 kN) once, denoting a maximum efficiency. The obtained experimental results are utilized, in the framework of the present work, to calibrate contact parameters of nonlinear finite element models. The presented numerical results helped to assess benefits of the proposed configurations and the behavior of the anchorage components: the DA configuration turned out to satisfactorily avoid stress peak superpositions on the cable, with a reduction in pressure in the loading end of the cable with respect to the SA model.