2024
DOI: 10.1002/chem.202404206
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Frustrated Lewis Pairs from Al−E{14} Bonds (E{14}=Ge, Sn, Pb)

George W. A. Smith,
Samuel E. Neale,
Matthew J. Evans
et al.

Abstract: The potassium aluminyl K[Al(NON)] ([NON]2– = [O(SiMe2NDipp)2]2–, Dipp = 2,6‐iPr2C6H3) reacts with group 14 chloroamidinates E{14}(Am)Cl (E{14} = Ge, Sn, Pb. [Am]– = [tBuC(NDipp)2]–) to form (NON)Al–E{14}(Am) Lewis pairs with unsupported Al–E{14} bonds, including the first structurally authenticated Al–Pb bond. Analysis using spectroscopic (NMR, UV‐vis and Mössbauer for E{14} = Sn), X‐ray diffraction and computational (DFT, QTAIM, TD‐DFT) methods conclude an Al–E{14} σ‐bond derived from a Lewis basic Al and a L… Show more

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