2007
DOI: 10.1016/j.saa.2006.11.039
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FTIR spectra and mechanical strength analysis of some selected rubber derivatives

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Cited by 148 publications
(93 citation statements)
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“…According to spectra (Figure 2), the intensities of some bands were altered with the devulcanization process. Previous studies have attributed these IR bands to: (1) 1537 cm -1 : stretching vibration of a methyl-assisted conjugated double bond (" -(C=C) n -, where n > 6) from both NR [30,31] and SBR [32]; (2) deformation from NR rubber [31]; (3) 1076 cm -1 : symmetric C-S-C group stretching vibrations in the two C-S bonds [33]; (4) 1029 and 1006 cm -1 : C-S bonds [25]; (5) 962 cm -1 : -CH=CH-group vibrations of butadiene present in SBR [33,34]; and (6) 828 cm -1 : $ C-H bending from NR rubber [31]. The results reveal that the samples most exposed to microwaves had lower intensity bands, which was more evident in the GTR7 sample.…”
Section: Chemical Propertiesmentioning
confidence: 99%
“…According to spectra (Figure 2), the intensities of some bands were altered with the devulcanization process. Previous studies have attributed these IR bands to: (1) 1537 cm -1 : stretching vibration of a methyl-assisted conjugated double bond (" -(C=C) n -, where n > 6) from both NR [30,31] and SBR [32]; (2) deformation from NR rubber [31]; (3) 1076 cm -1 : symmetric C-S-C group stretching vibrations in the two C-S bonds [33]; (4) 1029 and 1006 cm -1 : C-S bonds [25]; (5) 962 cm -1 : -CH=CH-group vibrations of butadiene present in SBR [33,34]; and (6) 828 cm -1 : $ C-H bending from NR rubber [31]. The results reveal that the samples most exposed to microwaves had lower intensity bands, which was more evident in the GTR7 sample.…”
Section: Chemical Propertiesmentioning
confidence: 99%
“…Table 2. ATR-FTIR absorptions bands for graphene/EPDM-PAni, maleic anhydride treated EPDM and PAni synthesized without substrate and their assignments [52]. Table 3.…”
Section: Resultsmentioning
confidence: 99%
“…6 shows the spectra of graphene/EPDM-PAni, EPDM and PAni samples. In particular, the EPDM spectrum exhibits the characteristic bands of saturated C-H bounds: C-H symmetric and asymmetric stretching (2920 and 2850 cm -1 ), C-H 2 scissoring (1461 cm -1 ), CH 3 bending (1375 cm -1 ), and -(CH 2 -CH 2 ) -backbone (720 cm -1 ) [52]. PAni synthesized without substrate showed the following bands: stretching of quinoid ring (1598 cm -1 ), stretching of benzenoid ring (1496 cm -1 ), C-N stretching (aromatic amines) + C-C bending (1302 cm -1 ), C-N stretching (aliphatic amines) + C-C stretching (1245 cm -1 ) and Q=H stretching + =Q-stretching (1121 cm -1 ) where Q is a quinon group [28,53].…”
Section: Fourier Transform Infrared Spectroscopy (Ftir)mentioning
confidence: 99%
“…antisymmetric stretching vibrations of -CH 2 - [22]. It can be seen that the absorption peaks corresponding to methyl (CH 3 -) and methylene (-CH 2 -) groups appear in the spectrum of the stearic-acid modified specimen, but not in that of the unmodified specimen.…”
Section: Methodsmentioning
confidence: 94%