Fulgides and Fulgimides

Renth, Falk; Temps, F.

doi:10.1002/9783527827626.ch9

Cited by 5 publications

(2 citation statements)

References 70 publications

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“…Among the extensively explored photoactive modules, 21–24 tetra-coordinate organoboron compounds which are more recently discovered, exhibit versatile and highly adjustable properties. 25 These units have been effectively utilized to synthesize a diverse array of photo-responsive entities, extending from small molecules 26 to hybrid photosensitive molecules, 27 transition metal complexes, 28 lanthanide compounds 29 and macromolecules.…”

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confidence: 99%

“…14,15 To date, numerous photoactive gelators have been explored, with a primary focus on the use of several well-studied photochromic building blocks, including azobenzene, 16,17 spiropyran, 18 and diarylethene. 19,20 Among the extensively explored photoactive modules, [21][22][23][24] tetracoordinate organoboron compounds which are more recently discovered, exhibit versatile and highly adjustable properties. 25 These units have been effectively utilized to synthesize a diverse array of photo-responsive entities, extending from small molecules 26 to hybrid photosensitive molecules, 27 transition metal complexes, 28 lanthanide compounds 29 and macromolecules.…”

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Organoboron based photochromic gelator

Zhang,

Zhao,

Yin

et al. 2024

Chem. Commun.

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Organoboron based photochromic gelator

Zhang,

Zhao,

Yin

et al. 2024

Chem. Commun.

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Fulgide Derivatives as Photo‐Switchable Coatings for Cathodes of Lithium Ion Batteries – A DFT Study

Dietrich,

Cisternas

2024

ChemPlusChem

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Photo‐switchable coatings for lithium ion batteries (LIB) can offer the possibility to control the diffusion processes from the electrode materials to the electrolyte and thus, for example, reducing the energy loss in the fully charged state. Fulgide derivatives, as known photo‐switches, are investigated concerning their use as coating for vanadium pentoxide, a potential cathode material for LIB. With the help of Density Functional Theory calculations, two fulgide derivatives are characterized with respect to their photophysics, their aggregation behaviour on the cathode material and the ability to form self‐assembled monolayers (SAM). Furthermore, the two states of the photo‐switchable coating are tested with respect to lithium diffusion from the cathode material, passing the SAM and entering the electrolyte. We found a difference for the energy barriers depending on the state of the photo‐switch, preferring its closed form. This behaviour can be used to prevent the loss of charge in batteries of portable devices.

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