This paper presents two original methods for monitoring and evaluating concrete specimens/structures affected by external sulfate attack (ESA). The first is a drying method developed to assess the penetration depth of sulfate ions in a concrete structure, as this parameter is a relevant indicator of the progress of the ESA. This method has been specifically designed for on-site investigations. The second experimental method involves the use of optical fibers capable of measuring the swelling response of specimens to ESA in real time. According to the results obtained, these two new methods seem likely to be used to complement or replace traditional methods such as inductively coupled plasma (ICP) for determining the penetration depth of sulfate ions or as extensometers for measuring swelling. These traditional methods (ICP and extensometers) are generally considered painful and time-consuming, whereas, because of its simplicity, the proposed drying method will enable experts to regularly inspect concrete structures and make informed decisions on the measures to be taken to repair or prevent further damage induced by ESA, while the second method appears promising for experimental studies involving the monitoring of a large number of ESA-affected specimens.