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NRC Publications Record / Notice d'Archives des publications de CNRC:http://nparc.cisti-icist.nrc-cnrc.gc.ca/eng/view/object/?id=5c9e5f2f-e987-427a-a147-3f9bc515eded http://nparc.cisti-icist.nrc-cnrc.gc.ca/fra/voir/objet/?id=5c9e5f2f-e987-427a-a147-3f9bc515eded ABSTRACT: Fully printed thin film transistors (TFT) based on poly(9,9-di-n-dodecylfluorene) (PFDD) wrapped semiconducting single walled carbon nanotube (SWCNT) channels are fabricated by a practical route that combines roll-to-roll (R2R) gravure and ink jet printing. SWCNT network density is easily controlled via ink formulation (concentration and polymer:CNT ratio) and jetting conditions (droplet size, drop spacing, and number of printed layers). Optimum inkjet printing conditions are established on Si/SiO 2 in which an ink consisting of 6:1 PFDD:SWCNT ratio with 50 mg L −1SWCNT concentration printed at a drop spacing of 20 μm results in TFTs with mobilities of ∼25 cm 2 V −1 s −1 and on-/offcurrent ratios > 10 5 . These conditions yield excellent network uniformity and are used in a fully additive process to fabricate fully printed TFTs on PET substrates with mobility values > 5 cm 2 V −1 s −1 (R2R printed gate electrode and dielectric; inkjet printed channel and source/drain electrodes). An inkjet printed encapsulation layer completes the TFT process (fabricated in bottom gate, top contact TFT configuration) and provides mobilities > 1 cm 2 V −1 s −1 with good operational stability, based on the performance of an inverter circuit. An array of 20 TFTs shows that most have less than 10% variability in terms of threshold voltage, transconductance, on-current, and subthreshold swing.