Functional‐Group‐Induced Single Quantum Well Dion–Jacobson 2D Perovskite for Efficient and Stable Inverted Perovskite Solar Cells

Gong, Cheng; Chen, Xihan; Zeng, Jie; Wang, Huaxin; Li, Haiyun; Qian, Qingkai; Zhang, Cong; Zhuang, Qixin; Yu, Xuemeng; Gong, Shaokuan; Yang, Hua; Xu, Baomin; Chen, Jiangzhao; Zang, Zhigang

doi:10.1002/adma.202307422

Cited by 19 publications

(1 citation statement)

References 41 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…41 Beside determining the n phases through structural stability, the hydrogen bonding between cations like dimethyl adipimidate can induce uniformly distributed colloidal sizes in precursor solution and result in spontaneously formed phase-pure 2D perovskite at the bottom of 3D perovskite thin films. 42 The other factor that influences the n values in 2D/3D heterojunctions is the lattice matching between 2D and 3D structures. 43 A large lattice mismatch caused by the differences in halides and cations in 2D and 3D perovskites results in lattice strain at the interfaces, which facilitates the maintenance of the pre-crystallized n = 1 2D crystal in its original phase when incorporated into the 3D perovskite matrix, as phase transformation is less favorable.…”

Section: Structural Characteristics Of 2d/3d Heterojunctionmentioning

confidence: 99%

Advances and challenges in molecular engineering of 2D/3D perovskite heterostructures

Ma,

Sun,

Dou

2024

Chem. Commun.

View full text Add to dashboard Cite

show abstract

Section: Structural Characteristics Of 2d/3d Heterojunctionmentioning

confidence: 99%

Advances and challenges in molecular engineering of 2D/3D perovskite heterostructures

Ma,

Sun,

Dou

2024

Chem. Commun.

View full text Add to dashboard Cite

show abstract

Buried Interface‐The Key Issues for High Performance Inverted Perovskite Solar Cells

Yan,

Fang,

Dai

et al. 2024

Adv Funct Materials

View full text Add to dashboard Cite

Interface engineering is known for effectively improving interfacial contact and passivating defects to enhance device performance of inverted perovskite solar cells (PSCs). Currently, most of works focus on surface passivation, while the buried interface is equally important. The film quality of perovskite layer greatly relies on the buried interface, leaving a pronounced impact on overall device performance. In addition, resolving defects and energy level mismatch at buried interface remains challenging. Optimizing the buried interface becomes a promising approach for high‐efficiency inverted PSCs. This review summarizes recent advances in buried interface engineering and emphasize the importance of corresponding characterization techniques. The various functions of buried interface engineering are carefully discussed, including crystallization modulation, defect passivation, energy level alignment, chemical reaction inhibition, chemical bridge, dipole cancellation and novel buried interfacial techniques. Finally, current challenges and prospects are put forward that should be addressed to further improve device performance of inverted PSCs.

show abstract

Enhancing Durability of Organic–Inorganic Hybrid Perovskite Solar Cells in High‐Temperature Environments: Exploring Thermal Stability, Molecular Structures, and AI Applications

Su,

Ahn,

Yang

2024

Adv Funct Materials

View full text Add to dashboard Cite

The commercialization of perovskite solar cells (PSCs), as an emerging industry, still faces competition from other renewable energy technologies in the market. It is essential to ensure that PSCs are durable and stable in high‐temperature environments in order to meet the varied market demands of hot regions or seasons. The influence of high temperatures on the PSCs is complex, encompassing factors such as lattice strain, crystal phase changes, the creation of defects, and ion movement. Furthermore, it intensifies lattice vibrations and phonon scattering, which in turn impacts the migration rate of charge carriers. This review focuses on the durability of organic–inorganic hybrid PSCs under high temperatures. It begins by analyzing the impact of external temperature variations on the internal energy dynamics of PSCs. Subsequently, it outlines the various mechanisms provided by different functional molecules, applied to interface stabilization, grain boundary passivation, crystal growth control, electrode protection, and the development of new hole transport layers, to enhance the thermal stability of PSCs. Additionally, machine learning (ML) is discussed for predicting crystal structure stability, PSCs operational stability, and material screening, with a focus on the potential of deep learning and explainable artifical intelligence (AI) techniques in the commercialization of PSCs.

show abstract

Functional‐Group‐Induced Single Quantum Well Dion–Jacobson 2D Perovskite for Efficient and Stable Inverted Perovskite Solar Cells

Cited by 19 publications

References 41 publications

Advances and challenges in molecular engineering of 2D/3D perovskite heterostructures

Advances and challenges in molecular engineering of 2D/3D perovskite heterostructures

Buried Interface‐The Key Issues for High Performance Inverted Perovskite Solar Cells

Enhancing Durability of Organic–Inorganic Hybrid Perovskite Solar Cells in High‐Temperature Environments: Exploring Thermal Stability, Molecular Structures, and AI Applications

Contact Info

Product

Resources

About