Functionalized Carbon Nanotubes for Ammonia Sensors

Srinivasreddy, Rakshith K.; Kadeppagari, Ravi-Kumar

doi:10.1002/9783527830978.ch10

Cited by 1 publication

(1 citation statement)

References 66 publications

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“…Conversely, the increase in sensor resistance during ammonia adsorption by CNFs is caused by the electron donating nature of ammonia, adsorption of which reduces the concentration of charge carriers (holes, namely) leading to a decrease in conductivity. At the same time the investigated CNF samples contain not so much centers of ammonia interacting with surface compared to other carbon materials (e.g., graphene [58], graphene oxide [59], graphite oxide [60], functionalized carbon nanotubes [61] etc.) and this explains their low response to NH 3 .…”

Section: Gas Sensing Propertiesmentioning

confidence: 96%

Carbon Nanofibers Synthesized at Different Pressures for Detection of NO2 at Room Temperature

et al. 2023

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In this paper, room-temperature chemiresistive gas sensors for NO2 detection based on CVD-grown carbon nanofibers (CNFs) were investigated. Transmission electron microscopy, low-temperature nitrogen adsorption, and X-ray diffraction were used to investigate the carbon nanomaterials. CNFs were synthesized in a wide range of pressure (1–5 bar) by COx-free decomposition of methane over the Ni/Al2O3 catalyst. It was found that the increase in pressure during the synthesis of CNFs induced the later deactivation of the catalyst, and the yield of CNFs decreased when increasing pressure. Sensing properties were determined in a dynamic flow-through installation at NO2 concentrations ranging from 1 to 400 ppm. Ammonia detection was tested for comparison in a range of 100–500 ppm. The obtained sensors based on CNFs synthesized at 1 bar showed high responses of 1.7%, 5.0%, and 10.0% to 1 ppm, 5 ppm, and 10 ppm NO2 at 25 ± 2 °C, respectively. It was shown that the obtained non-modified carbon nanomaterials can be used successfully used for room temperature detection of nitrogen dioxide. It was found that the increase in relative humidity (RH) of air induced growth of response, and this effect was facilitated after reaching RH ~35% for CNFs synthesized at elevated pressures.

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