Here, a zinc-based metal–organic framework-decorated
graphene
oxide (MOF@GO) nanocomposite was synthesized and incorporated within
a polyacrylonitrile (PAN) nanofibrous filter to enhance the particulate
matter (PM) removal efficiency. For this purpose, the PAN nanofibrous
filters containing different contents of the MOF@GO nanocomposite
(PAN/MOF@GO) were fabricated, and their morphology was studied using
field-emission scanning electron microscopy. The results revealed
the formation of uniform and bead-free nanofibers with the MOF@GO
wrapping tightly around them. The resultant nanofibrous filters were
evaluated for PM removal and possible breath monitoring. The results
revealed good mechanical properties with freestanding ability and
hydrophobic behavior of the PAN/MOF@GO nanofibrous filters, indicating
the possibility of long-term application in high humidity conditions.
More importantly, the optimized PAN/MOF@GO nanofibrous filter exhibited
a high PM filtration efficiency (95.13%), low pressure drop (15.29
Pa), and superior quality factor (0.198 Pa–1). Moreover,
the electrical resistance of the PAN/MOF@GO nanofibrous filter changed
with different breathing patterns, indicating the possibility of using
the developed nanofibrous filter for human respiration monitoring.
This work provides new insights into the fabrication of nanofibrous
filters with boosted performance for PM removal by the synergistic
effect of GO and MOF particles.