Functionalized oxathiacrown macrocycles: Synthesis, characterization and coordination to palladium(II), ruthenium(II) and copper(I)

Carel, Guillaume; Madec, David; Saponar, Alina; Saffon, Nathalie; Nemeş, Gabriela; Rima, G.; Castel, Annie

doi:10.1016/j.jorganchem.2014.01.002

Cited by 9 publications

(1 citation statement)

References 37 publications

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“…Among the large variety of ligands used for these complexes are for example different phosphines, [15] sulfoxides, [16] Schiff bases [17] or pincer ligands. [13,14,[18][19][20] Furthermore, the preparation of ligands with properties modulated by the presence of several functional groups like: metallylenes, [21][22][23] oxathia-derivatives, [24] germil-aminophosphoric esters, [25] phophaalkenyl derivatives [26][27][28] or organometallic halogenated derivatives [29][30][31] as well as their study for the stabilization of transition metals derivatives of palladium, ruthenium, gold, tungsten, etc., is a continuous concern in our team.…”

Section: Introductionmentioning

confidence: 99%

Palladium and Ruthenium Derivatives Stabilised by bis-Sulfone Ligand

Deak¹,

Septelean²,

Moraru³

et al. 2018

Studia UBB Chemia

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The synthesis and characterization of new palladium and ruthenium derivatives using the bis-sulfone 1,3-bis{(4-methylphenyl)sulfonyl}-5-tert-butylbenzene ligand is presented. The new compounds were characterized in solution by multinuclear NMR spectroscopy and for the palladium derivative the molecular structure in solid state was also determined by single crystal X-ray diffraction. The work was completed with a DFT study in order to better understand the electronic effect in the stabilization of the new complexes containing bis-sulfone ligand.

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