The neutral gas in the atmosphere has a significant effect on signals passing through it. We are concerned with three types of effects. First, the large-scale structures in the media give rise to refractive effects. These effects, which can be analyzed in terms of geometrical optics and Fermat's principle, are the deflection of the radio waves and the change of the propagation velocity. Second, radiation can be absorbed. Finally, radiation can be scattered by the turbulent structure of the media. The phenomenon of scattering results in scintillation, or seeing.In the troposphere, water vapor plays a particularly important role in radio propagation. The refractivity of water vapor is about 20 times greater in the radio range than in the near-infrared or optical regimes. The phase fluctuations in radio interferometers at centimeter, millimeter, and submillimeter wavelengths are caused predominantly by fluctuations in the distribution of water vapor. Water vapor is poorly mixed in the troposphere, and the total column density of water vapor cannot be accurately sensed from surface meteorological measurements. Uncertainties in the water vapor content are a serious limitation to the accuracy of VLBI measurements. Small-scale (< 1 km) fluctuations in water vapor distribution limit the angular resolution of connected-element interferometers in the absence of wavefront correction techniques. Furthermore, spectral lines of water vapor cause substantial absorption at frequencies above 100 GHz and usually render the troposphere highly opaque at frequencies between 1 and 10 THz (300 and 30 m). Thus, any discussion of the neutral atmosphere must be primarily concerned with the effects of water vapor. Propagation in the neutral atmosphere from the point of view of radio communications is discussed by Crane (1981) and Bohlander et al. (1985).Our interest in the propagation media arises because the media degrade interferometric measurements of radio sources. Alternately, observations of radio sources can be used to probe the characteristics of the propagation media. Radio interferometric measurements have been used widely for this purpose.