We investigate production processes of Ti+ in magnetron sputtering plasmas to explain the finding that Ti+ density is enhanced significantly in the downstream region of a high-pressure discharge [N. Nafarizal et al.: Jpn. J. Appl. Phys. 44 (2005) L737]. We examined the contributions of the following five production processes: 1) electron impact ionization (Ti+e→Ti++2e), 2) Penning ionization (Ti+ArM→Ti++Ar+e), 3) charge exchange collision with Ar+ (Ti+Ar+→Ti++Ar), 4) three-body recombination (Ti2++e+e→Ti++e), and 5) two-step ionization via metastable Ti (Ti+e→TiM+e followed by TiM+e→Ti++2e). However, the experimental results indicated that none of the five processes listed above was the dominant production mechanism of Ti+ in the high-pressure magnetron sputtering plasma. We consider charge exchange collision with Ar2+ (Ti+Ar2+→Ti++2Ar) as a possible mechanism that explains the increase in Ti+ density in the high-pressure discharge.