IntroductionCarbon-based symmetrical electrochemical double-layer capacitors (EDLCs) demonstrate higher energy density and power capability in organic-based electrolytes compared to aqueous-based electrolytes owing to their high operating voltage (2.5-2.7 V). Indeed, despite a lower capacitance of carbon-based electrodes in organic electrolytes (C), the maximum energy density (E max ) is expressed asand is proportional to the square of the maximum operating voltage (U max ), which is limited to the water electrochemical stability window that cannot theoretically exceed 1.23 V. Thus, even if the capacitance of a symmetrical carbon-based device in an aqueous electrolyte is twice that of an EDLC in an organic electrolyte (C aq = 2C org ), the maximum operating voltage of an organic-based device is more than twice that of an aqueous-based capacitor (U org = 2U aq ) resulting in:Obviously, this simple calculation does not take into account additional factors such as electrolyte concentration, ionic conductivity, packaging, and so on, but some more detailed theoretical calculation [1] points out the superiority of symmetrical carbon-based EDLC in an organic electrolyte (5.7 vs 1.7 Wh kg −1 for symmetrical carbon-based devices in aqueous electrolytes). Practically, the superiority of organicbased carbon/carbon devices has been demonstrated and most commercial-based devices use organic electrolytes. However, aqueous-based devices possess a number of advantages that can be emphasized in a commercial system, such as their high ionic conductivity, which can be useful to achieve high power density [2,3]. In addition, the electrothermal safety of aqueous-based devices will be greater in all cases than for organic-based electrolytes [4], which is one of the major points now addressed by electrochemical capacitor (EC) manufacturers as high currents and fast cycling rates are usually required, thus possibly leading to thermal rather than chemical runaway of the