This article proposes a methodology to prepare polymer dispersed liquid crystal (PDLC) films working in the reverse-mode operation, where the ion-doped nematic liquid crystals (NLCs) with negative dielectric anisotropy (Δε) were locked by polymer walls. On-state and off-state of films were controlled by an electric field. In the absence of an electric field, it appears to be transparent. In the field, the homogeneous alignment NLCs form dynamic scattering, giving rise to opaque. The effect of the cylindrical holes with different diameters of photo masks and liquid crystal Δε on the electro-optical properties and transmittance wavelength range of 400-3000 nm light of samples were investigated. It was found that it exhibited very good electro-optical characteristics, high contrast ratio and excellent infrared energy-efficient of films used as switchable windows.Keywords: reverse-mode polymer dispersed liquid crystal; polymer walls; nematic liquid crystal; negative dielectric anisotropy; electro-optical properties
IntroductionPolymer dispersed liquid crystal (PDLC) films are technologically important class of materials that find numerous applications as electrically switchable optical devices.[1-3] PDLC films are formed by liquid crystal (LC) microdroplets embedded in a polymer matrix. They can exhibit either a droplet morphology in which droplets of LC are embedded in a polymer matrix, or a polymer ball morphology in which the LC takes up the voids and the crevices of a network structure formed by small polymer balls. In the normal-mode operation, they are in an opaque state (offstate) and can be turned into a transparent state (onstate) by controlling the LC molecule orientation by means of a suitable voltage. The reverse-mode PDLC films are transparent in its off-state and can be turned into an opaque on-state. A greater interest has been aroused by reverse-mode PDLC films that are useful as switchable windows, automotive applications [4,5] and used in a wide range of applications that need a transparent state in the absence of any applied voltage.Several authors have reported examples of reverse-mode PDLC films obtained by modification of the polymer surface energy,[6] by functionalising the LC/polymer matrix interface,[7] by using dualfrequency addressable LC,[8] by means of rough surfaces [9,10] or by increasing the LC content. [11]