When nitrogen and nitrogen+oxygen mixtures, in the pressure range 1-750 mm Hg are excited by soft X-rays, the strongest emission features in the visible and ultra-violet spectrum are the second positive bands (C3nU-B3ng of N2) and first negative bands (B2';st-X2Zg of N ; ) . Intensity measurements show that the NZ B state is deactivated in approximately every collision with ground-state nitrogen and oxygen molecules, if normal gas-kinetic cross-sections are assumed ; this is also true of the N2 C state in collision with oxygen, while the cross-sections for deactivation by nitrogen are about one-thirtieth and onetenth of the gas-kinetic cross-section, for v' = 0 and 1 respectively.