“…Sensing using optical methods has been an active field of research in recent years [1][2][3], due to the inherently superior capabilities offered by complex photonic structures [4,5]. Specifically, microstructures incorporated within optical fiber tapers transmitting near-infrared (NIR) light have found comprehensive applications in a variety of sensing scenarios, including in liquid [6][7][8][9], gas [10,11], and other physical [12][13][14][15][16] and chemical [17,18] media. In particular, the chemically inert nature of silica fiber [19] and Si substrates [20] makes their combination a leading platform for integration with reactive layers for controllable chemically-sensitive response tailored to vapor specificity [21,22], and measuring additional quantities such as temperature together with the vapor content [23].…”