Thermal imaging cameras and infrared (IR) temperature measurement devices act as state-of-the-art techniques for non-contact temperature determination of the skin surface. The former is cost-intensive in many cases for widespread application, and the latter requires manual alignment to the measuring point. Due to this background, this paper proposes a new method for automated, non-contact, and area-specific temperature measurement of the facial skin surface. It is based on the combined use of a low-cost thermopile sensor matrix and a 2D image sensor. The temperature values as well as the 2D image data are fused using a parametric affine transformation. Based on face recognition, this allows temperature values to be assigned to selected facial regions and used specifically to determine the skin surface temperature. The advantages of the proposed method are described. It is demonstrated by means of a participant study that the temperature absolute values, which are achieved without manual alignment in an automated manner, are comparable to a commercially available IR-based forehead thermometer.