Inclusion of kinetic isotope effects (KIEs) of methane (CH4) sinks (gaseous OH and C1, and soil microbes) has a significant effect on modeled distributions of 613C of atmospheric CH 4. For a given scenario of surface sources and corresponding 6•3C values of individual CH 4 sources, the KIE due to soil uptake enriched 613C by 1.18%o in the model's northern hemisphere (NH) (40øN) and 1.16%o in the southern hemisphere (SH) (40øS) under steady state conditions in January. The KIE due to CH 4 oxidation by stratospheric C1 radicals further enriched these 6•C values at the surface by 0.99%• and 1.03%•, respectively. In the vertical direction, during January at 50øN, inclusion of a KIE due to C1 enriched 6•C at 18 km by 0.95%• compared to the corresponding surface value, whereas the enrichment was only 0.31%• when this KIE was omitted. These results suggest that modeling of 6•3C distributions should include KIEs due to CH 4 oxidation by soil and stratospheric chlorine radicals. It is shown that possible oxidation of CH 4 in marine boundary layer by C1 radicals can significantly enrich 6•3C. However, if a recent theoretical value for the KIE of the C1 and CH 4 reaction is correct, then the impact of this reaction is less than the figures quoted above. In the model, monthly variations in OH concentration and interhemispheric exchange transport cannot reproduce the observed seasonal amplitude variation of 6•3C in either the NH or SH. It is argued that seasonal variations in individual CH 4 fluxes are primarily responsible for this discrepancy. We show that increasing C1 radical concentrations due to continued release of anthropogenic chlorocarbons enrich the 6•3C values. The effects of an increase in tropospheric OH concentration due to stratospheric ozone depletion and a cooling of the troposphere due to the eruption of Mt. Pinatubo, with a lowering of water vapor concentration and reduction in isoprene emissions, on 6•C and surface CH 4 mixing ratios are investigated. Other model simulations with adjusted surface CH 4 fluxes have been performed to study the postulated explanations for recent changes in CH 4 surface mixing ratios and •3C values. A modified version of the Oslo two-dimensional global tropospheric photochemical model was used for all simulations. Introduction The importance of atmospheric methane (CH4) is well established [see Ehhalt, 1974; Cicerone and Oreroland, 1988], for example, its role as a radiative trace gas in global warming [Ramanathan et al., 1985; Dickinson and Cicerone, 1986] and its importance in tropospheric and stratospheric chemistry [Crutzen and Schmailzl, 1983; Thompson and Cicerone, 1986; Isaksen and Hov, 1987; Crutzen, 1987]. Measurements of atmospheric CH 4 in air trapped in ice cores show that during the last 150 years CH 4 surface concentration has increased by a factor of 2 [Etheridge e! al., 1992]. Continuous direct surface measurements since 1978 show a consistent upward trend in CH 4 concentration of about 1% per year at least through 1984 [Rasmussen and Khalil, 1981; Steele et al...