A new type of bre Raman laser composed of a GeO 2 -and P 2 O 5 -doped silica bre was investigated experimentally and theoretically. The output of the laser displays two di erence characteristics depending on the type of bre being used as the input end. Using the P 2 O 5 -doped bre as the input end, the Raman Stokes line of 1320 cm 1 shift was enhanced by the latter GeO 2 -doped bre. While the GeO 2 -doped bre used as the input end, a wideband continuous spectrum was obtained. A model including e ects of bandwidth of the Raman gain, four-wave mixing and the mutual in uence of the GeO 2 -and P 2 O 5 -doped silica bre was constructed to illustrate the experimental observation.
IntroductionStimulated Raman scattering (SRS) in optical bres has been researched intensively for over two decades [1][2][3]. The relevant applications cover many elds from optical communication, bre sensor to nonlinear spectroscopy. In the research of biophotonics and photodynamic diagnostics, tunable coherence sources operating around 600 nm are needed. The photon energy of this wavelength region is high enough to activate the photosensitizer e ciently and not too high to cause serious self-uorescence of tissue. A bre Raman laser pumped by a doublefrequency Nd:YAG laser is a potential candidate for this purpose with the advantages of good beam quality, easy handling and long lifetime. Among the various types of Raman bre used today [4-6], GeO 2 -doped (germanosilicate or G-doped) and P 2 O 5 -doped (phosphosilicate or P-doped) silica bres attract most attention. GeO 2 -doped silica bres have a broad Raman gain spectrum with the peak at 440 cm 1 , the same as that for a pure silica bre. The amplitude of Raman gain in the G-doped bre is proportional to the doping ratio and the Raman gain of pure GeO 2 is nine times that of pure SiO 2 material [7]. The Raman gain spectrum of P 2 O 5 -doped bres has two peaks at 440 and 1320 cm 1 which correspond to the vibrational band of SiO 2 and P 2 O 5 respectively [8]. It can be found that the third Raman order of GeO 2 coincide with the rst Raman order of P 2 O 5 . This coincidence, involving other nonlinear processes, such as four-wave mixing (FWM) [9], self-phase modulation (SPM) and cross-phase modulation (XPM) [10], will lead to a unique output of the composite P-and G-doped bre. In this paper, SRS for the composition of these two bres is investigated for the rst time