The main implication of articulating electrolyte performance is studying the energy density, charging aspects, formation of precipitates, thermal fluctuations during charging−discharging, and safety of batteries against fire or spark. One of the most significant aspects is the ability to design colloidal electrolytes that can enhance the overall performance of batteries along with dealing with all internal problems within a battery system. Through this optimization progression, the general performance and efficiency of Li-ion batteries can be improved. This work is presented in the study of the boundary value problem for rheological properties of colloidal electrolytes as a fourth grade fluid for lithium ion (Li-ion) batteries down a vertical cylinder. They have exceptional characteristics, such as low volatility and high thermal stability. The practical usage of the exact flow is restricted, as it involves very complicated integrals. The nonlinear problem that arises is solved by Galerkin's finite element approach based on the weighted-residual formulation, which is used to find the approximate solutions of the fourth-grade problem. This approach utilizes a piecewise linear approximation using linear Lagrange polynomials. Convergence of the solutions, which briefly describes the flow characteristics, includes the effects of the emerging parameters. The results obtained after implementation are not restrictive to small values of the flow parameters. Numerical studies have shown the superior accuracy and lesser computational cost of this scheme in comparison to collocation, the homotopy analysis method, and the homotopy perturbation method. The impact of the relevant parameters is examined through graphical results after implementation of a number of iterations.