The implementation of energy-saving policies has stimulated
intensive
interest in exploring self-powered optoelectronic devices. The 2D
p-n homojunction exhibits effective generation and separation of carriers
excited by light, realizing lower power consumption and higher performance
photodetectors. Here, a self-powered photodetector with high performance
is fabricated based on an F4-TCNQ localized molecular-doped lateral
InSe homojunction. Compared with the intrinsic InSe photodetector,
the switching light ratio (I
light/I
dark) of the p-n homojunction device can be
enhanced by 2.2 × 104, and the temporal response is
also dramatically improved to 24/30 μs. Benefiting from the
built-in electric field, due to the formation of an InSe p-n homojunction
after partial doping of F4-TCNQ on InSe, the device possesses a high
responsivity (R) of 93.21 mA/W, with a specific detectivity
(D*) of 1.14 × 1011 Jones. These
results suggest a promising approach to get a lateral InSe p-n homojunction
and reveal the potential application of the device for next generation
low-consumption photodetectors.