2020
DOI: 10.3390/coatings11010009
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Galvanic Corrosion Performance of an Al–BN Abradable Seal Coating System in Chloride Solution

Abstract: In this study, we investigated the galvanic corrosion performance of an Aluminum–Boron Nitride (Al–BN) abradable seal coating system (with a Ni5Al bond layer and a 0Cr17Ni4Cu4Nb substrate) in chloride solution by electrochemical methods. The results indicated a three-stage process occurred during the anodic dissolution of the coupled coating system, consisting of a spontaneous pitting stage I under charge transfer control with a decreasing rate, a corrosion developing stage II under mass transfer control with … Show more

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Cited by 8 publications
(3 citation statements)
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“…Once corrosive mediums reach Al/coating interface, corrosion reactions occur on the aluminium substrate, leading to a complete destruction of the protective performance of the WPU coating. In addition, a specific corrosion phenomenon of Al and its alloys is the increase of cathodic hydrogen evolution rate under anodic polarization of the electrode resulting from the combined effects of the local pH drop and the passive film breakdown, which is often referred to as the "negative difference effect" (NDE), [18][19][20] meaning it is contrary to the prediction in electrochemical theory that the hydrogen evolution rate should decrease with increasing anodic polarization. 21 The presence of H 2 gas at the metal/coating interface poses a significant challenge to coating adhesion and ultimately results in the rapid failure of the WPU coating.…”
Section: Introductionmentioning
confidence: 93%
“…Once corrosive mediums reach Al/coating interface, corrosion reactions occur on the aluminium substrate, leading to a complete destruction of the protective performance of the WPU coating. In addition, a specific corrosion phenomenon of Al and its alloys is the increase of cathodic hydrogen evolution rate under anodic polarization of the electrode resulting from the combined effects of the local pH drop and the passive film breakdown, which is often referred to as the "negative difference effect" (NDE), [18][19][20] meaning it is contrary to the prediction in electrochemical theory that the hydrogen evolution rate should decrease with increasing anodic polarization. 21 The presence of H 2 gas at the metal/coating interface poses a significant challenge to coating adhesion and ultimately results in the rapid failure of the WPU coating.…”
Section: Introductionmentioning
confidence: 93%
“…Meanwhile, annealing at 600 °C enhanced the Rct slightly but lowered the Rf. The presence of an inductive loop presented by an inductance Lf in the equivalent circuit is mainly associated with the phenomena of species absorption such as intermediate corrosion products, metallic chloride, hydrated metal hydroxides, and chemical species such as chloride ions [24], but it can also be associated with partial anodic dissolution [24], as well as the film breakdown due to corrosion [25]. This trend can be described according to the following reactions: After being immersion for 24 h in 3 wt% NaCl solution at 30 °C with pH 4, the FE-SEM images showed that all specimen surfaces had been corroded, and part of the surface layer had been dissolved (figures 10(a)-(g)).…”
Section: Corrosion Behaviormentioning
confidence: 99%
“…It was found that the corrosion resistance was remarkably improved by WC compared to the base alloy [ 19 ]. The Al-BN system was also tested in a chloride solution to evaluate the galvanic corrosion performance [ 20 ].…”
Section: Introductionmentioning
confidence: 99%