The Indo-Gangetic Plains (IGP) experience
high levels of airborne
particulate matter (PM), especially during the dry season. Contributing
to PM are natural and anthropogenic emissions and the atmospheric
transformation of gases to form particles. Regional smog events occur
frequently during wintertime and provide an atmospheric medium for
aerosol processing. Here, we investigate the chemical composition
and sources of PM at a representative site in the northern IGP during
the second Nepal Ambient Monitoring and Source Testing Experiment
(NAMaSTE 2). In Lumbini, Nepal, the 24 h average PM2.5 and
PM10 concentrations ranged 48–295 and 60–343
μg m–3, respectively, from December 20, 2017,
to January 1, 2018. On average (± standard deviation), PM2.5 was composed of 39 ± 7% organic carbon (OC), 5 ±
2% elemental carbon (EC), and 20 ± 6% secondary inorganic ions
(ammonium, nitrate, and sulfate), 2.0% chloride, and 1.3% potassium.
Biomass burning was a major PM source, indicated by a median levoglucosan
concentration of 3.5 μg m–3. Secondary organic
aerosol (SOA) derived from biomass burning was indicated by high concentrations
of nitromonoaromatic compounds (e.g., 4-nitrocatechol peaking at 435
ng m–3). During periods of fog, characterized by
high relative humidity (RH) and relatively low solar radiation, nitroaromatic
concentrations dropped despite levoglucosan remaining high, indicating
that their formation was suppressed. Chemical signatures of SOA indicated
that volatile organic compound (VOC) precursors were primarily combustion-derived,
with small contributions from biogenic VOC. Through molecular markers
and chemical mass balance (CMB) modeling, sources of PM2.5 OC were identified as cow dung burning (24 ± 16%), other biomass
burning (20 ± 7%), plastic/garbage burning (4.7 ± 3.2%),
vehicle emissions (3.1 ± 1.4%), coal combustion (0.3 ± 0.2%),
and SOA from monoaromatic VOC (4.1 ± 0.8%), diaromatic VOC (8.9
± 4.0%), cresol (0.3 ± 0.4%), isoprene (0.4 ± 0.2%),
monoterpenes (1.5 ± 0.6%), and sesquiterpenes (3.2 ± 0.7%).
Understanding the levels of PM in Lumbini, along with its chemical
composition and sources of OC, contributes to a better understanding
of regional air quality episodes in the IGP.