Generation of X-rays: general concepts and terminologyX-rays are produced by the collision of high-velocity electrons with a stationary or rotating metallic target. The most useful X-rays for the home laboratory have energies between 4 and 21 keV, which relates to wavelengths of 3.1-0.59 Å (1 Å = 10 −10 m). X-rays with energy below 4 keV are readily absorbed by air, while X-rays above 21 keV will return condensed powder patterns that can be difficult to interpret.In practice, the metallic target is made of chromium (Cr), cobalt (Co), copper (Cu) or molybdenum (Mo). These metals produce X-rays in the 4-21 keV range while providing stable heat conduction and corrosion resistance. The production of X-rays generates large quantities of heat, which must be dissipated rapidly in order to prevent the metallic targets from melting; therefore, the metals must be durable and conductive to both heat and electricity.The continuous and characteristic spectrum of X-ray radiation is produced when highvelocity electrons strike the metallic target. The continuous spectrum or Bremsstrahlung radiation is produced when the path of the electron that enters the target is altered by interactions with the metal atoms (McCall, 1982). The bending or braking action causes the electrons to lose momentum and release X-ray radiation. The Bremsstrahlung radiation displays a continuous spectrum due to the fact that not every electron will decelerate in a similar manner. The electrons that are completely stopped by the impact will release all of their energy at once, and thus produce the maximum energetic and lowest wavelength X-ray. The energy is thus described by the equation:where λ is in Å (10 −10 m) and V is the applied voltage. If one plots the intensity of the Bremsstrahlung radiation against increasing wavelength, one would etch a curve that begins at λ min and rapidly increases to a maximum of a few tenths of an Angstrom above λ min and then slowly decreases as one proceeds to longer wavelengths. The characteristic spectrum, on the other hand, is composed of sharp intensity maxima at critical wavelengths and is superimposed on the continuous spectrum. These narrow peaks are characteristic of the metal used in the target material and are associated with the Principles and Applications of Powder Diffraction. Edited