To improve the selectivity and yield
of multiphase reactions, an
attempt to intensify gas–liquid mass-transfer operations was
undertaken in which screen/grid static mixers were used to promote
interphase mass transfer. A modified technique was used to enhance
the reproducibility of the results and to account for the depletion
effect which becomes critical at high mass-transfer rates. The volumetric
mass transfer coefficient, k
L
a, was found to increase with increasing liquid superficial velocity
and gas volume fraction and reached values as high as 4.08 s–1 at low specific energy consumption rates, particularly for slowly
coalescent systems, a situation that is encountered in most industrially
relevant systems. The gas–liquid reactor/contactor presently investigated takes
advantage of the coalescence retardation characteristics of most industrially
relevant streams to achieve k
L
a values that surpassed those of most conventional reactor/contactors
by more than an order of magnitude while maintaining a high energy
utilization efficiency (up to 0.63 kg O2/kWh). The ability
to reach 98% equilibrium within residence times of less than 800 ms,
achieved without significantly increasing the power consumption rates,
allows for the use of static mixing reactor volumes that are several
orders of magnitude smaller than conventional units such as mechanically
agitated tanks and bubble columns.