There are a substantial number of chemical engineering processes requiring the intimate contact of a gas with a liquid in which a finely divided solid is suspended. Present techniques often require extensive equipment and maintenance in order to obtain the desired product. In purely diffusive or mass transfer operations, such as those involving absorption of a gas into a slurry of an absorbent and subsequent adsorption of the dissolved gas, the equivalent of a countercurrent multistage operation will be required if an appreciable percent removal of solute gas from the feed mixture is expected. The multistage agitated column shown in Figure 1, originally designed by Oldshue and Rushton (1 952) for liquid-liquid extraction, was investigated for use as such a countercurrent gas-slurry contactor.
Experimental Equipment and ProcedureThe column is a 0.1524 m dia., 13-stage, fully baffled, mechanically agitated vessel employing countercurrent flow of gas with a liquid-solid slurry. The stages are 0.0834 m in height and are formed by stainless steel annular baffles having a central opening of 0.0826 m dia. The top stage is 0.4752 m in height in order to allow space for liquid and solid feeding. Each stage was agitated with a 0.0508 m dia., six-blade, flat disc type turbine with blades 0.0127 m wide and 0.0095 m high.Work was done using water slurries of limestone, sulfur, coal, and PVC pellets of varying particle sizes. The solid properties of interest are listed in Table 1. The water slurries were premixed, and were fed and removed from the top and bottom of the column using constant-volume displacement Moyno pumps.Air, a t rates measured by a rotameter, entered the column through a side port in the bottom stage. As the air was being dispersed, the liquid level in the column was maintained by an overflow port in the top stage. No collection of air was necessary a t the top of the column.Volume samples of the slurry feed and discharge streams were measured, filtered, dried, and weighed to determine the solid volume percent of the two streams. Approximately five turnovers of the column were required before these samples became equal, indicating steady state conditions, a t which point the Moyno pumps and air inlet valves were shut down simultaneously. After clearing all the air from the column, the liquid level was recorded to determine the gas holdup by the bed expansion method. The holdup slurry was then removed, agitated to uniformity in a smaller tank from which samples were taken, and analyzed as above to determine the volume percent solid holdup based on the liquid and solid volume only. The uniformity of the mixture in the sampling tank was periodically checked by weighing the entire solid holdup removed from the column after oven drying for a number of runs for each solid used. The range of conditions studied within the 13-stage column are listed in Table 2.The mechanical power input, being a better indicator of the degree of mixing than the impeller speed, was also investigated using a geometrically similar three...