Gas-Phase-Induced Engineering for Fabrication of 3D Hierarchical Porous Nickel and Its Application toward High-Performance Supercapacitors

Abstract

Commercial nickel foam (NF), which is composed of numerous interconnected ligaments and hundred-micron pores, is widely acknowledged as a current collector/electrode material for catalysis, sensing, and energy storage applications. However, the commonly used NF often does not work satisfactorily due to its smooth surface and hollow structure of the ligaments. Herein, a gas-phase-induced engineering, two-step gaseous oxidation−reduction (GOR) is presented to directly transform the thinwalled hollow ligament of NF into a three-dimensional (3D) nanoporous prism structure, resulting in the fabrication of a unique hierarchical porous nickel foam (HPNF). This 3D nanoporous architecture is achieved by utilizing the spontaneous reconstruction of nickel atoms during volume expansion and contraction in the GOR process. The process avoids the involution of acid−base corrosion and sacrificial components, which are facile, environmentally friendly, and suitable for large-scale fabrication. Furthermore, MnO 2 is electrochemically deposited on the HPNF to form a supercapacitor electrode (HPNF/MnO 2 ). Because of the fully open structure for ion transport, superhydrophilic properties, and the increased contact area between MnO 2 and the current collector, the HPNF/MnO 2 electrode exhibits a high specific capacitance of 997.5 F g −1 at 3 A g −1 and remarkable cycling stability with 99.6% capacitance retention after 20000 cycles in 0.1 M Na 2 SO 4 electrolyte, outperforming most MnO 2 -based supercapacitor electrodes.